Applying acrylic concrete stains is simple for the do-it-yourselfer. There are couple ways, but always be sure to stir the stain periodically during application.

Use a brush to cover the corners and edges first. Then roll the rest with a short-medium nap roller making all strokes in the same direction. A nylon brush can be used for smaller areas. Let it dry for three hours and apply a second coat by rolling in the opposite direction. As a general rule, one gallon will cover 200-300 sq ft. Rough surfaces require more stain than smooth surfaces. Allow another three hours for the second coat to dry and wash the concrete with soap and water.
Tips
If you're doing large areas it makes more sense to spray the stain. This is the method I prefer to use. The result is a more mottled appearance due to the uneveness of the application.
All you need is a cheap garden pump srayer with the tip adjusted for a fine mist. Don't be afraid if you leave some minor puddling as this adds to a more natural, variegated look.
The only drawback to spraying is having to protect walls and surroundings from overspray.
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